Olympiakos 0 - 1 Roma
Perrotta 76 (R)
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Simone Perrotta's goal conquered Athens as Roma won 1-0 at Olympiakos to give themselves a good chance of progressing in Europe.
The Giallorossi faced their second consecutive away match, having lost 2-1 at Valencia, but were more hopeful of picking up points in Greece. Francesco Totti and Matteo Ferrari shook off knocks, but Roma were without Amantino Mancini, David Pizarro, Philippe Mexes and Vincenzo Montella, so Ricardo Faty received his Champions League debut. Olympiakos could count on ex-Milan star Rivaldo and former Inter man Grigorios Georgatos.
There was bad news within the opening minute, as Totti clutched the back of his thigh as he prepared to take a corner, as a flare exploded nearby and a shard struck him. The Roma captain was able to continue after treatment.
Max Tonetto was booked for a foul on Castillo and Djordjevic drilled over the bar from distance before Alexander Doni rushed off his line to close down Castillo.
Totti nearly took advantage of a Nikopolidis error, but the Giallorossi were let off on 28 minutes when Kostantinou turned in from a free kick after it had hit the bar, but it was disallowed for an Anatolakis handling offence in the build-up.
Rodrigo Taddei's cross-shot skimmed the frame of the goal and a weak Rivaldo effort was comfortably held by his fellow Brazilian. Cristian Chivu performed a crucial tackle as Castillo set up Kafes, but Doni was required soon after to parry a wonderful solo effort from Uruguayan starlet Castillo.
Olympiakos were pushing harder towards the break and hit the crossbar again, this time with Konstantinou's header from a Rivaldo free kick.
Into the second half and Roma seemed to regain their composure, Totti firing a spectacular effort over the bar.
Chivu's curling left-foot free kick was palmed out with some difficulty by Nikopolidis on the hour mark and some delightful Taddei footwork - sliding the ball under the sole of his boot - kept the move going and his shot was charged down.
Aleandro Rosi replaced Marco Cassetti in midfield when the ex-Lecce man suffered from cramp, Olympiakos substitute Maric fired off target on the counter-attack, but it was the visitors who broke the deadlock on 76 minutes.
Simone Perrotta scored the first goal Roma have ever netted on Greek soil. Totti and Rosi combined at pace and the ex-Chievo midfielder came sliding in at the near post to finish the move.
Totti thought he'd snatched a second goal in stoppages when he pounced on a defensive error, but his softly-struck angled drive was inches past the far post of an empty net.
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Olympiakos: Nikopolidis; Zewlakow, Anatolakis, Julio Cesar, Georgatos; Castillo, Kafes (Maric 61), Stoltidis, P Djordjevic (Okkas 70); Rivaldo (Borja 82); M Konstantinou
Roma: Doni; Panucci, Ferrari, Chivu, Tonetto; De Rossi; Cassetti (Rosi 66), Faty (Aquilani 77), Perrotta, Taddei (Defendi 92); Totti
Ref: Poll (Eng)